The 22nd James Bond film, Quantum Of Solace, will feature a theme song duet for the first time in the franchise's history.
Jack White (of the White Stripes and Raconteurs) and Alicia Keys will record Another Way To Die.
As rumoured, troubled British chanteuse Amy Winehouse had been in talks to record a song that didn't progress.
Producers Michael G Wilson and Barbara Broccoli of EON confirmed that White and Keys had already recorded the new song, which White wrote and produced and for which he also plays drums.
Quantum Of Solaceis out in November and the J Records soundtrack will be out Oct 28.